N-(2,6-Dimethylphenyl)succinamic acid
نویسندگان
چکیده
In the amide segment of the title compound, C(12)H(15)NO(3) {systematic name: 3-[(2,6-dimethyl-phen-yl)amino-carbon-yl]propionic acid}, the N-H and C=O bonds are anti to each other. The mol-ecules are packed into a two-dimensional array via N-H⋯O and O-H⋯O hydrogen bonds.
منابع مشابه
N-(3,4-Dimethylphenyl)succinamic acid
The asymmetric unit of the title compound, C(12)H(15)NO(3), contains two independent mol-ecules. In both mol-ecules, the conformations of the amide oxygen and the carbonyl O atom of the acid segment are anti to the adjacent CH(2) groups. In the crystal, both molecules form inversion dimers linked by pairs of O-H⋯O hydrogen bonds and N-H⋯O interactions link the dimers into [100] chains.
متن کاملN-(3,5-Dimethylphenyl)succinamic acid
In the title compound, C(12)H(15)NO(3), the N-H and C=O bonds are anti to each other. The C=O and O-H bonds of the acid group display an anti-periplanar orientation relative to each other. The crystal packing features a three-dimensional network of molecules held together by O-H⋯O and N-H⋯O hydrogen bonds.
متن کاملN-(2,3-Dimethylphenyl)succinamic acid
In the title compound, C(12)H(15)NO(3), the conformations of N-H and C=O bonds in the amide segment are anti to each other and that of the amide H atom is syn to the ortho- and meta-methyl groups in the benzene ring. In the crystal, the mol-ecules are linked into infinite chains through inter-molecular O-H⋯O and N-H⋯O hydrogen bonds.
متن کاملN 1,N 2-Bis(2,6-dimethylphenyl)-N 1-hydroxyformamidine N,N′-bis(2,6-dimethylphenyl)-N-oxidoformamidinium dichloromethane solvate
The title compound, 2C(17)H(20)N(2)O·CH(2)Cl(2), was obtained by N-oxidation of the parent formamidine with m-chloro-peroxy-benzoic acid (m-CPBA). This is the first use of the above-mentioned synthetic route for the preparation of hydroxy-amidines. The title compound crystallizes as a cyclic dimer resulting from the presence of O-H⋯O and N-H⋯N hydrogen bonds.
متن کاملN-(2,6-Dimethylphenyl)-2-methylacetamide
The structure of the title compound (26DMPMA), C(11)H(15)NO, is closely related to the side-chain unsubstituted N-(2,6-dimethyl-phen-yl)acetamide and side-chain substituted N-(2,6-dimethyl-phen-yl)-2,2,2-trimethyl-acetamide and 2-chloro-N-(2,6-dimethyl-phen-yl)acetamide, with slightly different bond parameters. The mol-ecules in 26DMPMA are linked into chains through N-H⋯O hydrogen bonding.
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